The best thing to do is choose a few songs and put them on your iPod in all the different formats you are considering. Then listen to the same song in the different formats and see whether if like the lower bit rate version or if you must have the higher bit rate version.
Personally, I use (good quality) Bose on-ear headphones, a Bose speaker dock and a Klipsch speaker dock. Most of my songs are in 192kbps AAC, some are 256kbps and I don't hear the difference. But then, my age means that my hearing is no longer as acute as it was.
Since you have a 160GB iPod, if you have the room (that is, not too many songs), use the higher bit rate. I began using the higher bit rate when I realised I had the room.
Phil
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